Path: utzoo!utgpu!jarvis.csri.toronto.edu!mailrus!purdue!tut.cis.ohio-state.edu!zaphod.mps.ohio-state.edu!sunybcs!kitty!larry From: larry@kitty.UUCP (Larry Lippman) Newsgroups: sci.bio Subject: Re: Omega-3 fatty acids Summary: YASCN (Yet Another Scheme for Chemical Nomenclature) Keywords: unsaturated fatty acids Message-ID: <3534@kitty.UUCP> Date: 3 Dec 89 05:20:29 GMT References: <859@wrgate.WR.TEK.COM> <3531@kitty.UUCP> <25773343.1707@rpi.edu> Organization: Recognition Research Corp., Clarence, NY Lines: 29 In article <25773343.1707@rpi.edu>, jdh@pawl.rpi.edu (Joseph Herrenkohl) writes: > The symbol omega refers to the position of a double bond in unsaturated > fatty acids. Usually the numbering scheme is based on the carboxyl group > and the position(s) of the double bond(s) are indicated by the superscript > delta. However an alternative (archaic?) scheme numbers from the terminal > methyl carbon - the position is then indicated by omega. For example, > linoleic acid is (delta)9,12-octadecadienoic acid or (omega)6,9- > octadecadienoic acid. Oh, great - another scheme for chemical nomenclature. :-) Pardon me for a moment while I air a pet gripe. As far as I know, fatty acids haven't changed in the past 20 years since I've been out of college - so why should the nomenclature change? As I learned it, linoleic acid was alternatively referred to by the designation 9,12-octadecadienoic acid. Period. No delta in front of the 9,12 and no alternative omega scheme. As a point of comparison, linolenic acid (three double carbon bonds) is 9,12,15-octadecatrienoic acid. Now, if one wanted to be a IUPAC purist, one would merely write these fatty acids as cis,cis-9,12-octadecadienoic acid or cis,cis,cis-9,12,15-octadecatrienoic acid. What could be *simpler*? <> Larry Lippman @ Recognition Research Corp. - Uniquex Corp. - Viatran Corp. <> UUCP {allegra|boulder|decvax|rutgers|watmath}!sunybcs!kitty!larry <> TEL 716/688-1231 | 716/773-1700 {hplabs|utzoo|uunet}!/ \uniquex!larry <> FAX 716/741-9635 | 716/773-2488 "Have you hugged your cat today?"