Xref: utzoo alt.paranormal:1430 bionet.neuroscience:61 bionet.sci-resources:299 Path: utzoo!utgpu!news-server.csri.toronto.edu!rpi!think.com!snorkelwacker.mit.edu!ira.uka.de!fauern!math.fu-berlin.de!tmpmbx!zelator!leo From: leo@zelator.uucp (Stefan Hartmann) Newsgroups: alt.paranormal,bionet.neuroscience,bionet.sci-resources,maus.umwelt Subject: free energy news (measurements results) Summary: free energy technology Keywords: free energy Message-ID: Date: 20 May 91 19:35:17 GMT Distribution: alt Organization: Puplic-Access-Xenix Lines: 1051 Workshop for decentral energy research e.V. proudly presents: ------------------------------------------------------------- ****************************************************************************** * How to win FREE energy with an * * Adiabatic-isochoric-adiabatic-isochoric cycle over labile states of the * * P-V-diagram * ****************************************************************************** from B.Schaeffer and W.D.Bauer DKOWA Gmbh Pasewaldtstr.7 W-1000 Berlin 37, Germany keywords: free energy, violation of the second law of thermodynamics, spontaneous condensation,thermodynamic cycle, second law of thermodynamics Abstract: Measurements with a benzene-water mixture at 154 deegrees Celsius show that a adiabatic-isochoric-adiabatic-isochoric cycle through the supersaturated states of the vapour phase during expansion allows a machine to be built, which in contrary to an equilibrium cycle does not need two temperature poles, but only one. Other substances will be proposed, which allow the same process to proceed at environmental temperatures. Thus it will be possible to build a refrigirator which produces electrical power when operated ! 1.Introduction The concept of entropy was created by R.Clausius. He showed that the expression for the entropy dS=dQ/T=(dU+PdV)/T applied to an ideal gas leads to the result that S is a potential. With the development of the first real equations of state the usual concept of entropy was again introduced. However, in deriving thermodynamic potentials the assumption was then built into the theory that the entropy has to be a potential[1]. Regarding dynamic phenomena of phase transitions (for instance spontaneous condensation), however, the potential concept of entropy becomes senseless, because the labile states a gas can reach with a fast adiabatic expansion do not fulfil a unique equation of state. Thus, the thermodynamic potentials become ambiguous and lose the mathematical character of a potential. Therefore, the question arises, whether the second law of thermodynamics (in the versions of Planck[2] and Caratheodory[3]) remains valid for labile states. We will answer this question in this article empirically with a clear NO ! 2.Experimental procedure In order to test the dynamic P-V-behaviour of vapours as working media in machines we built an apparatus, which consisted of a cylinder with a movable piston, see fig.1. The diameter of the piston was 10 cm. The starting volume was 10 cm3 ,the end point volume was 1200 cm3. At the entry of the cylinder there was a valve, which opened and closed the conduit pipe from the boiler which contained a heating coil with a maximum power of 300 W. The fluid (300 cm3 benzene (Merck), 3 l bidistilled water) was cycled continously through glass beads in order to get a uniform evaporation of the non-miscible fluids, see fig.1. Boiler and cylinder were embedded in a heat insulation. The piston of the cylinder was driven by a second larger piston moving in a cylinder(diameter 14 cm), whose pressure was delivered from a 12 bar compressor. The velocity of compression could be regulated by needle valves in the exhausts of both sides of the driving cylinder. The housing of the cylinder with the smaller piston was thermostated by cycling the fluid of the boiler through it with a pump. The difference in temperature between inlet and outlet was about 0.1 degrees Celsius. The temperature of the lid of the cylinder could be regulated separately by a thermostated electric heating of maximal 100 W power. Cooling down could be improved by removing the heat insulation. In order to measure the pressure a fast piezoelectric sensor was built into the lid of the cylinder. It showed maximum deviations of 0.01 bar when measuring the adiabate of air. Data collection and regulation of the apparatus were achieved with a personal computer. 3.Measurement At a fixed temperature of 154 degrees Celsius and a pressure of 11.4 bar the starting point was set. Then the valve to the cylinder was closed and the piston was expanded over about 0.3 sec, see fig.2. First the pressure went down and then rose again to a certain level with an increase in volume. In most cases a maximum was reached and the curve went slowly down until it reached the end point. At the end point of the expansion a pause interval of 3 sec was set. This time was the optimum to get a maximum decrease in pressure about 4 bar. Then the piston was recompressed in a time of 0.3 sec and reached again the starting volume. The pressure at this point was slightly higher than the starting volume, but decayed and reached again the starting level after some seconds. The net work area of this cycle was typically 200-300 J. A necessary condition to get these results was that the lid of the cylinder was cooler than the housing (optimum difference 4 degrees Celsius). Performing periodically cycles with the cylinder closed the net work area decreased in time, but after refreshing the vapour by opening the valves of the cylinder the higher values could be achieved again. 4.Discussion a)experimental Our apparatus has the disadvantage that the pressure of the cycle can not be measured under conditions when the pressure is higher than the starting pressure. Nevertheless, it can be shown that with this cycle a net work yield is obtained. If we assume that the pressure of the working medium before reaching the end point would be so high that the work area becomes zero or even reverses sign, then the excess pressure pex can be estimated from the formula pex=work area/(vB-vA). Inserting values from fig.2 (work area 452 J,vB-vA=30cm3) we get an excess pressure pex of over 100 bar. This would overcome the driving compressor or would exceed the absolute maximum ratings of the apparatus which is designed for a maximum pressure of 20 bar. Neither is the case. It can also be shown that the small temperature gradient in the cylinder cannot be responsible for the work produced in the cycle. If we assume that the cycle is driven by this difference T1-T2 it would have an efficiency | of | = (Q2-Q1)/Q2 = (T2-T1)/T2 = -W/Q2 , where Q1/2 are the heats and T1/2 temperatures and -W the work. Then our machine would have an efficiency | of |< 1%. This means for the cycle of fig.2 that heat amounts of at least Q2>45.2KJ and Q1<-44.75KJ would be exchanged between the wall and the working medium (mass<10 g) in about 4 sec. These amounts of heat are enough to heat up or to cool down the temperature of the fluid of the whole boiler (mass=3.3 kg) by about 3 oC, where we assumed, that the temperature change could proceed during the cycle in 4 sec instead of some minutes as actually observed by the temperature detection system of the thermostat (sampling time 1 sec) in the lid. Both heatings of our system (together max. 400 W) are too weak to compensate such amounts of heat in these times. The temperature difference works as a cooling trap collecting fluid in the cylinder and is responsible for the point where the evaporation begins in the expansion phase, but has nothing to do with the production of work in the sense of a Carnot cycle. Even if we accept the opinion that the work is due to the temperature difference, then the observed over-Carnot efficiency means that, according to the considerations of the Carnot theorem, in a machine this temperature difference could be maintained by a part of the work the machine delivers [1]. From this follows that the second law of thermodynamics is in fact violated. b)theoretical We explain the measured cycle in the following manner: The fast decay at the beginning of the expansion adiabate is "normal" adiabatic behaviour of the gas. The increasing pressure with increasing volume expansion is caused by the evaporation of the fluid under vacuum situated mainly on the warm wall of the lid. If the evaporated fluid enters the cylinder it becomes labile. The plateau region of the pressure and the often following slow decrease is caused by the dynamic equilibrium between evaporating fluid and expanding volume. The breakdown of the pressure at the end point of the expansion is due to the return to equilibrium. There are two different ways to explain qualitatively the labile state of the expansion adiabate. The first is the hypothesis of Doczekal[4], which says that benzene and water have different temperatures at the end of the adabatic expansion. For this interpretation some arguments can be found. The vapour pressure curve of water-benzene mixtures can be calculated simply, like ideal gases, by adding the partial pressure of water and benzene respectively [5]. This means that the gases are independent and do not interact because of the hydrophobicity of the benzene. The diffusion and the heat exchange between water and benzene is therefore hindered. Thus, in a fast adiabatic expansion both gases have different temperatures at the end point. The second usual way to explain the expansion adiabate is that both components are at one temperature in the supersaturated and supercooled state and return to equilibrium via spontaneous condensation [6][7][8], changing the pressure energy of the gas into inner heat. The higher pressure at the end of the compression adiabate can be understood more easily. It is caused first by the fact that during the time interval between expanding and compressing heat enters the cylinder, and second by the fact that in a fast compression the applied energy is unequally distributed between the fluid and the gas because of the different moduli of compression. Now we have to characterize the difference between our cycle and the carnot cycle, see fig.3a-c: At the beginning of the cycle the working medium is in thermal contact with the environment. This means in our case that the working medium of the cylinder is connected to the boiler as environment. Then the working medium is decoupled from the environment, i.e. the valve is closed. The first three steps of the cycle, including the isochoric part1), we assume to proceed totally adiabatically (dQ=0), because in effect no amount of heat can be exchanged in this short times with the environment. Assuming the first law of thermodynamics to be valid, we have to conclude that the temperature level of the working medium should be lower, when the piston reaches again the the end point A of the cylinder, because a net amount of work has been subtracted from the internal energy of the medium during the cycle. In order to close the cycle the cooled down working medium is brought again in contact with the environment (i.e. we open again the valve to the boiler) and after an isochoric influx of heat, the working medium reaches again the original temperature of the environment. The efficiency | of such a cycle should be 1. 5.Outlook The described adiabatic-isochoric-adiabatic-isochoric cycle needs only one heat reservoir in contrary to an equilibrium cycle. Our system, however, is not directly suited to building a machine which gains energy from cooling down the environment, because the starting temperature of the cycle is too high. Therefore, we have to look for substances, which show similar behaviour to benzene - water but at environmental temperatures. ________________________________________________________________________________ Footnote: 1) The word isochoric (dV=0) we have taken over from equilibrium thermodynamics. One should be aware of the difference that in equilibrium thermodynamics an isochoric change of state is bound to an exchange of energy with the working medium. We see here that in non-equilibrium thermodynamics this has not to be the case. ________________________________________________________________________________ We looked for such substances with the following strategy: 1)The substances must not be hazardous to the environment. Regarding mixtures, the substances must not react chemically. 2)The critical temperature should not be too greatly in excess of the environment temperature. 3)The critical pressure should be high enough to allow enough energy to be produced. If one looks at well ordered tables of materials [9] one finds on the polar side methanol, ethanol and ammonia, on the non-polar side propane, ethane and carbon dioxide. Using binary and higher component mixtures of these substances it may be possible to adapt them to each technical problem. references: [1]Sommerfeld A., Thermodynamik und Statistik Harri Deutsch Frankfurt, Thun 1977 [2]Planck M., Vorlesungen ber Thermodynamik Leipzig 1897 [3]Caratheodory C.,Untersuchungen ber die Grundlagen der Thermodynamik. Math.Ann.67(1909),355-366 [4]Doczekal R., Deutsches Patent Zweigstelle sterreich 17.10.37 Nr.155744 [5]Karapetyants M. Kh., Chemical Thermodynamics Mir Publisher Moscow 1980 [6]Katz J.L.,Ostermier B.J., Journ.Chem.Phys. 47(2) (1967),478 [7]Zettlemoyer A.C.(ed.) Nucleation Phenomena Adv.Coll.Phen.7 Elsevier 1977 [8]Ehrler F., Spontane Kondensation VDI-Wrmeatlas 1988 VDI-Verlag Dsseldorf 1988 [9]Reid R.C.,Prausnitz J.M., Poling B.E. The properties of gases and liquids McGraw Hill New York 1986 [10]Schaeffer B.,Bauer W.D. How to win energy with an adiabatic-isochoric- adiabatic cycle over the labile states of the P-V-diagram WDB-Verlag Berlin 1990 figure legends: These pictures follow in an uuencoded file which is still packed with LHARC. These are fig1.pcx, fig2.pcx and fig3.pcx. You can view these Paintbrush (Z-Soft)-pics with any viewer which can handle PCX format. They are scanned black and white pics, no grayscale. Try it with vpic.exe, graphics workskop or the paintbrush.exe program within the windows 3.0 package on the PC. To unpack the pics: uudecode the scrambled ASCII-code and then type: lharc e pics.lzh fig.1: schematic sketch of the apparatus: 1)lid with heating and piezo-electric sensor 2)valve 3)static pressure sensor 4)boiler with heating and glass beads 5)pump 6)driving piston 7)position sensor 8)piston in cylinder fig.2: P-V-diagram of an adiabatic-isochoric-adiabatic-isochoric cycle going over supersaturated states in the expansion phase. Work yield 452J fig.3a: Realization of the adiabatic-isochoric-adabatic-isochoric cycle phase 1: coupling of the working medium to the environment fig.3b: Realization of the adiabatic-isochoric-adiabatic-isochoric cycle phase 2: decoupling from the environment, performing adiabatically the first three steps of the cycle and lowering the temperature of the medium fig.3c: Realization of the adiabatic-isochoric-adiabatic-isochoric cycle phase 3: coupling again the working medium to the environment, equating the temperature difference by an influx of heat into the working medium And now the pics: ************************cut here******************+ section 1 of uuencode 4.02 of file pics.lzh by R.E.M. begin 644 pics.lzh M'NLM;&@Q+8,W``"WU@``ZI&T%B``"$9)1S$N4$-8E2/+9'&X>,C`!%Y#FXFX- MO7,:"\#`@#"O%EC'6^Y9NB#W``K$&W1Q$Y8"U@%G@6J!9@+2!:0+*@59HAG++ M7ZT$J]%-BD^2@7K8#*&6=A@IDH6NQP>K13+Q+-X(0R@>\E=@84^.#;`J+7Q<'X3-Q0/C$7`(NK!S3A`/LC3. 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