Relay-Version: version B 2.10 5/3/83; site utzoo.UUCP Posting-Version: version B 2.10.2 9/5/84; site kitty.UUCP Path: utzoo!linus!decvax!ucbvax!ucdavis!lll-crg!seismo!rochester!rocksanne!sunybcs!kitty!larry From: larry@kitty.UUCP (Larry Lippman) Newsgroups: net.physics Subject: Re: Sub-zero Seltzer! Message-ID: <675@kitty.UUCP> Date: Mon, 30-Dec-85 16:32:01 EST Article-I.D.: kitty.675 Posted: Mon Dec 30 16:32:01 1985 Date-Received: Wed, 1-Jan-86 04:24:43 EST References: <601@hou2f.UUCP> Organization: Recognition Research Corp., Clarence, NY Lines: 26 > An unopened bottle of salt-free seltzer, kept overnight in > a sub-freezing room, remained liquid. I brought the bottle > into a warm room and immediately removed the twist-off cap. > Within seconds the liquid froze. Very dramatic! > > I can think of two contributing effects: > 1) The increased pressure within the bottle suppressed the > freezing point (as in regelation). When the pressure was > released, the water froze. > 2) The dissolved CO2 suppressed the freezing point. When the > gas escaped, the water froze. > > I think the second effect is the more important one. > Any comments? You got it - the reason is the presence of dissolved CO2 causing freezing point depression; the first reason is NOT a factor other than higher pressure causing more CO2 to remain in solution. The quantitative explanation for this phenomenon is expressed through Raoult's Law. ==> Larry Lippman @ Recognition Research Corp., Clarence, New York <== ==> UUCP {decvax|dual|rocksanne|rocksvax|watmath}!sunybcs!kitty!larry <== ==> VOICE 716/741-9185 {rice|shell}!baylor!/ <== ==> FAX 716/741-9635 {G1, G2, G3 modes} duke!ethos!/ <== ==> burl!gladys!/ <== ==> "Have you hugged your cat today?" ihnp4!/ <==